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71.
This work focuses on the reuse of grits waste, from cellulose industry, as a raw material to replace traditional carbonate material in ceramic wall tiles. Wall tile formulations bearing up to 15?wt% of the grits waste were prepared for replacement of calcareous. The tile manufacturing route consisted of dry powder granulation, uniaxial pressing, and firing at temperatures ranging from 1100?°C to 1180?°C by using a fast-firing cycle. The wall tile specimens were tested to determine their physical and mechanical properties (linear shrinkage, water absorption, apparent porosity, apparent density, breaking strength, and flexural strength). The firing behavior, phase transformations, and microstructure were evaluated by dilatometry, XRD, and SEM. The results showed that the fired wall tile specimens are composed of anorthite and quartz, as major mineral phases, and mullite as a minor phase. It was found that the grits waste had a positive influence on the properties and microstructure of the wall tile specimens. The results also revealed that the grits waste from cellulose industry could be used as a total replacement of traditional calcareous material in wall tile formulations. 相似文献
72.
La0.85DxSr0.15–xGa0.8Mg0.2O2.825 (D = Ba and Ca, x?=?0, 0.01, 0.03, 0.05, and 0.07) electrolytes were synthesized using a solid-state reaction method, calcined at 1400?°C for 5?h, and sintered at 1400?°C for 5?h. The microstructures, electrical properties, and cell performances of the electrolytes and fuel cells were analyzed by X-ray diffraction, scanning electron microscopy, impedance analysis, and electrochemical analysis. La0.85BaxSr0.15–xGa0.8Mg0.2O2.825 (LBSGM) and La0.85CaxSr0.15–xGa0.8Mg0.2O2.825 (LCSGM) exhibit a dense structure and a cubic perovskite phase. Further, they contain small amounts of a secondary phase. The lattice constants of LBSGM and LCSGM are 0.3913–0.3914?nm and 0.3906–0.3909?nm, respectively. The average grain size of the sample increases with increasing Ba2+ or Ca2+ content. The conductivity of LCSGM (0.197–0.174?S/cm) is usually higher than that of LBSGM (0.181–0.162?S/cm) at 800?°C. The cells with La0.85Sr0.15Ga0.8Mg0.2O2.825 and La0.85Ca0.03Sr0.12Ga0.8Mg0.2O2.825 electrolytes exhibit high open-circuit voltages and maximum power densities of 0.96?V and 542?mW/cm2 and 0.94?V and 567?mW/cm2, respectively, at 800?°C. 相似文献
73.
Enrico Kleebusch Christian Patzig Thomas Höche Christian Rüssel 《Ceramics International》2018,44(16):19818-19824
Glass-ceramics based on lithium-alumo-silicate glasses are commercially important for a wide range of applications, due to their special properties, like a vanishing thermal expansion. In order to tailor these properties, the composition of the glass and the temperature/time schedule are crucial factors. For the industrial production of most lithium-alumo-silicate glasses, high melting temperatures are required due to the high viscosities of the respective melt compositions. In this study, a simplified lithium-alumo-silicate glass composition with ZrO2 as nucleating agent, on the basis of the commercially available Robax® composition, is studied. Adding boron oxide leads to lower viscosities of the glass melt and notably lower melting temperatures may be supplied. The resulting glass is investigated using X-ray diffraction and transmission electron microscopy. During the crystallization process, phases such as ZrO2 and β-quartz types are formed. The microstructure of the glass ceramics is notably coarser than that of glass-ceramics which are obtained from lithium-alumo-silicate glasses of standard compositions. EDX-analyses indicate a considerable enrichment of chemical elements in comparatively small areas of the microstructure. Especially boron oxide is found to be enriched in the residual glass of the investigated glass-ceramics. 相似文献
74.
Yue Wang Jingyi Qiu Zhongbao Yu Hai Ming Meng Li Songtong Zhang Yusheng Yang 《Ceramics International》2018,44(2):1312-1320
Surface-interface reaction between the electrode and electrolyte plays a key role in lithium-ion storage properties, especially for high voltage cathode such as LiCoPO4 and Ni-riched cathode. Generally, surface modification is an effective method to improve the electrochemical performance of electrode materials. Herein, in order to revise the LiCoPO4 cathode with desirable properties, uniform AlF3-modified LiCoPO4 (LiCoPO4@AlF3) cathode materials in nano-sized distribution are synthesized. XRD result indicates that there is no structural transformation observed after AlF3 coating. TEM characterization and XPS analysis reveal that the surface of LiCoPO4 particle is coated by a nano-sized uniform AlF3 layer. Further, the electrochemical results indicate that AlF3 layer significantly improves the cycling and rate performances of LiCoPO4 cathode within the voltage range of 3.0–5.0 V. After a series of optimization, 4 mol% AlF3-coated LiCoPO4 material exhibits the best properties including an initial discharge capacity of 159 mA h g?1 at 0.1 C with 91% capacity retention after 50 cycles, especially a discharge capacity of 90 mA h g?1 can be obtained at 1 C rate. CV curves indicate that the polarization of cathode is reduced by AlF3 layer and EIS curves reveal that AlF3 layer relieves the increase of resistance to facilitate Li-ion transfer at the interface between electrode and electrolyte during the cycling process. The enhanced electrochemical performances are attributed to that the AlF3 layer can stabilize the interface between the cathode and electrolyte, form steady SEI film and suppress the electrolyte continuous decomposition at 5 V high voltages. This feasible strategy and novel characteristics of LiCoPO4@AlF3 could promise the prospective applications in the stat-art of special lithium-ion battery with high energy and/or power density. 相似文献
75.
L.C. Souza A.C.A. Silva N.O. Dantas P.C. Morais S.W. da Silva 《Ceramics International》2018,44(1):208-215
Successful fabrication of glass-based hybrid nanocomposites (GHNCs) incorporating Ag, core-shell CdSe/CdS and CdSxSe1?x nanoparticles (NPs) is herein reported. Both metallic (Ag) and semiconductor (CdSe/CdS) NPs were pre-synthesized, suspended in colloids and added into the sol-gel reaction medium which was used to fabricate the GHNCs. During fabrication of the nanocomposites a fraction (20–60%) of core-shell CdSe/CdS NPs was alloyed into CdSxSe1?x (0.20 < x < 0.35) NPs without changing morphology. Modulation of in situ alloying is possible via the relative content of organics added into the sol-gel protocol. Within colloids Ag (core-shell CdSe/CdS) NPs presented average diameter and polydispersity index of 49.5 nm (4.2 nm) and 0.41 (0.21), respectively. On the other hand, the Ag (core-shell CdSe/CdS) NPs’ average diameter and polydispersity index assessed from the GHNCs were respectively 51.5 nm (4.1 nm) and 0.43 (0.25), revealing negligible aggregation of the nanophases within the glass template. The new GHNCs herein introduced presented two independent excitonic transitions associated to homogenously dispersed semiconductor NPs, peaking around 420 nm (core-shell CdSe/CdS) and 650 nm (CdSxSe1?x) and matching the plasmonic resonance (Ag NPs) in the 400–500 nm range. We envisage that the new GHNCs represent very promising candidates for superior light manipulation while illuminated with multiple laser beams in quantum interference-based devices. 相似文献
76.
He Qi Ruzhong Zuo Jing-feng Li Longtu Li 《Journal of the European Ceramic Society》2018,38(16):5341-5347
A morphotropic phase boundary (MPB) between rhombohedral (R) and tetragonal (T) phases was identified in a few (0.9-x)NaNbO3-0.1BaTiO3-xABO3 (x?=?0–0.05) lead-free systems. Critical roles of R-phase inducers were specially evaluated in terms of phase boundary position, microstructure and piezoelectric responses. The results indicate not only the tolerance factor of the ABO3 additive but also its ferroelectricity and corresponding volume change would influence the formation of phase boundary and further determine dielectric and ferroelectric responses. The piezoelectric coefficient d33 of MPB compositions was compared with theoretically-calculated d33-cal according to d33?=?2Pr·ε33·Q33, demonstrating that the piezoelectric response of these systems should be determined by combined effects of the phase coexistence, nano-scale domains and particularly enhanced dielectric responses. The largest d33 ~305 pC/N, the highest ε33T/εo ~2815 and the lowest Pr ~14.7 μC/cm2 were achieved in the MPB composition with 3.75% SrZrO3. These experimental results provide a valuable reference for designing new NaNbO3-based lead-free piezoelectric materials. 相似文献
77.
78.
79.
Preethi Balasubramanian Teresa Büttner Valentina Miguez Pacheco Aldo R. Boccaccini 《Journal of the European Ceramic Society》2018,38(3):855-869
Boron is considered to influence the performance of several metabolic enzymes and boron deficiency is associated with impaired growth and abnormal bone development. As such, boron is a beneficial bioactive element for animals and humans. It is also well known that boron stimulates wound healing and improves bone health. The addition of boron in different proportions to bioactive glasses has significant effects on glass structure, glass processing parameters, biodegradability, biocompatibility, bioactivity and cytotoxicity. Different compositions of bioactive glasses (BGs) containing boron, including boron-doped, borosilicate and borate glasses, are being investigated for bone and soft tissue engineering under the premise that these BGs are suitable carriers of boron, indicating controlled release of B species in the biological environment. This paper reviews up to date research and applications of borate, borosilicate, and boron doped silicate and phosphate BGs focussing on their physical, structural, degradation and biological properties for hard and soft tissue regeneration. 相似文献
80.
Yiguang Jiang Benxue Jiang Qihua Zhu Nan Jiang Pande Zhang Shuilin Chen Xu Hu Ge Zhang Jintai Fan Liangbi Su Jiang Li Long Zhang 《Journal of the European Ceramic Society》2018,38(5):2404-2409
Different deformation rates of Nd,Y-codoped CaF2 transparent ceramics were prepared by ceramization of single crystals. The deformation rate effects on the crystallization behaviors, microstructures, mechanical properties, and optical performances were investigated for the first time. The results indicate that the comprehensive performances of Nd,Y-codoped CaF2 ceramic (△a?=?62%) are the most optimal compared with other ceramics having different deformation rates (△a?=?34%, 40%, 50%, and 75%). In further investigations of the optical properties, the Nd,Y-codoped CaF2 ceramic (△a?=?62%) sample exhibited a high transparency (Ta?>?91%, 3-mm thick,250?~?1200?nm), low light scattering, superior fracture toughness (K1c?~?0.71?MPa·m1/2), strong fluorescence emission, long lifetime (τ?=?348.72?μs), and broad FWHM (29.2?nm), promising a good candidate for high-power laser material. 相似文献